7Li nuclear magnetic resonance in the hexairon(III) antiferromagnetic molecular ring Fe6: Li

A. Lascialfari; F. Borsa; M. Corti; E. Micotti; Y. Furukawa; A. Cornia; D. Gatteschi

doi:10.1063/1.1687225

7Li nuclear magnetic resonance in the hexairon(III) antiferromagnetic molecular ring Fe6: Li

A. Lascialfari, F. Borsa, M. Corti, E. Micotti, Y. Furukawa, A. Cornia, D. Gatteschi

Istituto di Ricerche Farmacologiche "Mario Negri"

Research output: Contribution to journal › Article › peer-review

Abstract

The first NMR data of alkali-metal ion nuclei ( ⁷Li) in magnetic molecular rings was discussed. The Li nuclear magnetic resonance (NMR) spectra and nuclear pin-lattice relaxation rate (NSLR) measurements as a function of temperature from 1.5 to 50 K with applied field H = 1.5T were reported. It was found that the unsolved problem in magnetic rings was the determination of the temperature T spin dynamics and its effects on the nuclear relaxation. It was observed that the maxima in both Li and H NSLR pointed towards a slow electronic spin dynamics at temperatures of the order of J/k _b.

Original language	English
Pages (from-to)	6879-6881
Number of pages	3
Journal	Journal of Applied Physics
Volume	95
Issue number	11 II
DOIs	https://doi.org/10.1063/1.1687225
Publication status	Published - Jun 1 2004

ASJC Scopus subject areas

Physics and Astronomy (miscellaneous)
Physics and Astronomy(all)

Access to Document

10.1063/1.1687225

Cite this

@article{de86af5066eb4fd3bcd5b9bc1a3d45b1,

title = "7Li nuclear magnetic resonance in the hexairon(III) antiferromagnetic molecular ring Fe6: Li",

abstract = "The first NMR data of alkali-metal ion nuclei ( 7Li) in magnetic molecular rings was discussed. The Li nuclear magnetic resonance (NMR) spectra and nuclear pin-lattice relaxation rate (NSLR) measurements as a function of temperature from 1.5 to 50 K with applied field H = 1.5T were reported. It was found that the unsolved problem in magnetic rings was the determination of the temperature T spin dynamics and its effects on the nuclear relaxation. It was observed that the maxima in both Li and H NSLR pointed towards a slow electronic spin dynamics at temperatures of the order of J/k b.",

author = "A. Lascialfari and F. Borsa and M. Corti and E. Micotti and Y. Furukawa and A. Cornia and D. Gatteschi",

year = "2004",

month = jun,

day = "1",

doi = "10.1063/1.1687225",

language = "English",

volume = "95",

pages = "6879--6881",

journal = "Journal of Applied Physics",

issn = "0021-8979",

publisher = "American Institute of Physics Publising LLC",

number = "11 II",

}

TY - JOUR

T1 - 7Li nuclear magnetic resonance in the hexairon(III) antiferromagnetic molecular ring Fe6

T2 - Li

AU - Lascialfari, A.

AU - Borsa, F.

AU - Corti, M.

AU - Micotti, E.

AU - Furukawa, Y.

AU - Cornia, A.

AU - Gatteschi, D.

PY - 2004/6/1

Y1 - 2004/6/1

N2 - The first NMR data of alkali-metal ion nuclei ( 7Li) in magnetic molecular rings was discussed. The Li nuclear magnetic resonance (NMR) spectra and nuclear pin-lattice relaxation rate (NSLR) measurements as a function of temperature from 1.5 to 50 K with applied field H = 1.5T were reported. It was found that the unsolved problem in magnetic rings was the determination of the temperature T spin dynamics and its effects on the nuclear relaxation. It was observed that the maxima in both Li and H NSLR pointed towards a slow electronic spin dynamics at temperatures of the order of J/k b.

AB - The first NMR data of alkali-metal ion nuclei ( 7Li) in magnetic molecular rings was discussed. The Li nuclear magnetic resonance (NMR) spectra and nuclear pin-lattice relaxation rate (NSLR) measurements as a function of temperature from 1.5 to 50 K with applied field H = 1.5T were reported. It was found that the unsolved problem in magnetic rings was the determination of the temperature T spin dynamics and its effects on the nuclear relaxation. It was observed that the maxima in both Li and H NSLR pointed towards a slow electronic spin dynamics at temperatures of the order of J/k b.

UR - http://www.scopus.com/inward/record.url?scp=2942662124&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=2942662124&partnerID=8YFLogxK

U2 - 10.1063/1.1687225

DO - 10.1063/1.1687225

M3 - Article

AN - SCOPUS:2942662124

VL - 95

SP - 6879

EP - 6881

JO - Journal of Applied Physics

JF - Journal of Applied Physics

SN - 0021-8979

IS - 11 II

ER -

7Li nuclear magnetic resonance in the hexairon(III) antiferromagnetic molecular ring Fe6: Li

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this