Chromatographic study of thermal reactions of cis- and trans-[Coen2 (OCOC6H4X)2]NO3 complexes in the solid phase

V. Carunchio, G. Grassini Strazza, A. Messina, C. M. Polcaro

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Abstract

Thermal reactions of some cis- and trans-[Coen2(OCOC6H4X)2]NO3 complexes mixed with ammonium or sodium chloride, nitrate and sulphate are reported. Reflectance spectra have shown a cis to trans thermal isomerization and, in the presence of NH4Cl, the formation of trans-[Coen2Cl2]Y as final product. For the cis-isomers, the most interesting result is the chromatographic evidence of a stepwise reaction, resulting in the replacement of one carboxylato ligand by chloride and the formation of an intermediate species, characterized as trans-[Coen2(OCOC6H4X)Cl]Y. These intermediate species, are hardly detectable in the corresponding reactions of the trans-isomers. These results may mean that in the trans-carboxylato compounds the reaction rate of the second step is higher than that of the first, while the reverse can be supposed in the corresponding reaction of the cis-isomers.

Original languageEnglish
Pages (from-to)85-92
Number of pages8
JournalThermochimica Acta
Volume19
Issue number1
DOIs
Publication statusPublished - 1977

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ASJC Scopus subject areas

  • Chemistry (miscellaneous)
  • Physical and Theoretical Chemistry

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