Cyanide binding to phthalocyaninatoiron(II) in dimethyl sulfoxide in the presence of carbon monoxide: Kinetic and equilibrium study

Alberto Boffi, Claudio Ercolani, Fabrizio Monacelli, Paolo Ascenzi

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Kinetics and equilibrium measurements for the reversible binding of CN- to carbonylated phthalocyaninatoiron(II) ([Fe(pc)(CO)-(dmso)]) have been carried out, at 25.0°C in dimethyl sulfoxide. The rate of cyanide binding to [Fe(pc)(CO)(dmso)] is limited by the rate of CO dissociation and the ultimate formation of [Fe(pc)(CN)2]2- does not occur via [Fe(pc)(CO)(CN)]-. These results agree with a strong delabilization effect by CO on trans dmso. Implications of this effect are discussed.

Original languageEnglish
Pages (from-to)109-114
Number of pages6
JournalInorganica Chimica Acta
Volume267
Issue number1
Publication statusPublished - Jan 3 1998

Fingerprint

Dimethyl sulfoxide
Cyanides
cyanides
Carbon Monoxide
Dimethyl Sulfoxide
Carbon monoxide
carbon monoxide
Kinetics
kinetics
dissociation

Keywords

  • Cyanide complexes
  • Iron complexes
  • Kinetics and mechanism
  • Phthalocyanine complexes
  • Thermodynamics

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Cyanide binding to phthalocyaninatoiron(II) in dimethyl sulfoxide in the presence of carbon monoxide : Kinetic and equilibrium study. / Boffi, Alberto; Ercolani, Claudio; Monacelli, Fabrizio; Ascenzi, Paolo.

In: Inorganica Chimica Acta, Vol. 267, No. 1, 03.01.1998, p. 109-114.

Research output: Contribution to journalArticle

Boffi, Alberto ; Ercolani, Claudio ; Monacelli, Fabrizio ; Ascenzi, Paolo. / Cyanide binding to phthalocyaninatoiron(II) in dimethyl sulfoxide in the presence of carbon monoxide : Kinetic and equilibrium study. In: Inorganica Chimica Acta. 1998 ; Vol. 267, No. 1. pp. 109-114.
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