Dipolar field effects described by boson operators techniques: The case of intermolecular multiple-quantum coherences in liquids

W. Nosel, T. Gili, S. Capuani, B. Maraviglia

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Abstract

Dipolar couplings between macroscopically distant spins in solution nuclear magnetic resonance (NMR) are treated. We propose a novel technique to calculate the intermolecular multiple-quantum coherences (iMQCs) based on a boson operators approach. The choice of an annihilation and creation operator basis set allows us to produce a general expression of the NMR signal depending on local inhomogeneities of magnetic field. The general expression we derive fits into the well known background of iMQCs signal descriptions [J. Jeener, J. Chem. Phys. 112 (2000) 5091] and turns into the conventional quantum-mechanical Warren formulation [S. Lee, W. Richter, S. Vathyam, W.S. Warren, J. Chem. Phys. 105 (1996) 874] by means of appropriate approximations.

Original languageEnglish
Pages (from-to)452-456
Number of pages5
JournalChemical Physics Letters
Volume406
Issue number4-6
DOIs
Publication statusPublished - May 2 2005

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Condensed Matter Physics
  • Atomic and Molecular Physics, and Optics
  • Surfaces and Interfaces

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