Double resonance spectra of J-coupled I=1/2 and S=3 nuclear spins

Silvia Capuani, Francesco De Luca, Bruno Maraviglia

Research output: Contribution to journalArticle

Abstract

An extension of the Cartesian product operators formalism for scalar coupled I=1/2 and S=3 nuclear spins is proposed in order to predict the behavior of the function modulating the I spin echo amplitudes in spin-echo double resonance (SEDOR) experiments. With such an approach the coupling constant can be evaluated quite independently of the S=3 quadrupolar line broadening and magnetic field inhomogeneity. The method, which can be generalized to a wide class of molecules, is tested by the experimental behavior of the hydrogen SEDOR modulation by the 10B nuclei in Na210B 12H11SH.

Original languageEnglish
Pages (from-to)4521-4525
Number of pages5
JournalJournal of Chemical Physics
Volume101
Issue number6
Publication statusPublished - 1994

Fingerprint

nuclear spin
echoes
Hydrogen
Modulation
Magnetic fields
Molecules
inhomogeneity
scalars
formalism
modulation
operators
nuclei
Experiments
hydrogen
products
magnetic fields
molecules

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Capuani, S., De Luca, F., & Maraviglia, B. (1994). Double resonance spectra of J-coupled I=1/2 and S=3 nuclear spins. Journal of Chemical Physics, 101(6), 4521-4525.

Double resonance spectra of J-coupled I=1/2 and S=3 nuclear spins. / Capuani, Silvia; De Luca, Francesco; Maraviglia, Bruno.

In: Journal of Chemical Physics, Vol. 101, No. 6, 1994, p. 4521-4525.

Research output: Contribution to journalArticle

Capuani, S, De Luca, F & Maraviglia, B 1994, 'Double resonance spectra of J-coupled I=1/2 and S=3 nuclear spins', Journal of Chemical Physics, vol. 101, no. 6, pp. 4521-4525.
Capuani S, De Luca F, Maraviglia B. Double resonance spectra of J-coupled I=1/2 and S=3 nuclear spins. Journal of Chemical Physics. 1994;101(6):4521-4525.
Capuani, Silvia ; De Luca, Francesco ; Maraviglia, Bruno. / Double resonance spectra of J-coupled I=1/2 and S=3 nuclear spins. In: Journal of Chemical Physics. 1994 ; Vol. 101, No. 6. pp. 4521-4525.
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