Abstract
An extension of the Cartesian product operators formalism for scalar coupled I=1/2 and S=3 nuclear spins is proposed in order to predict the behavior of the function modulating the I spin echo amplitudes in spin-echo double resonance (SEDOR) experiments. With such an approach the coupling constant can be evaluated quite independently of the S=3 quadrupolar line broadening and magnetic field inhomogeneity. The method, which can be generalized to a wide class of molecules, is tested by the experimental behavior of the hydrogen SEDOR modulation by the 10B nuclei in Na210B 12H11SH.
| Original language | English |
|---|---|
| Pages (from-to) | 4521-4525 |
| Number of pages | 5 |
| Journal | Journal of Chemical Physics |
| Volume | 101 |
| Issue number | 6 |
| Publication status | Published - 1994 |
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ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
Cite this
Double resonance spectra of J-coupled I=1/2 and S=3 nuclear spins. / Capuani, Silvia; De Luca, Francesco; Maraviglia, Bruno.
In: Journal of Chemical Physics, Vol. 101, No. 6, 1994, p. 4521-4525.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Double resonance spectra of J-coupled I=1/2 and S=3 nuclear spins
AU - Capuani, Silvia
AU - De Luca, Francesco
AU - Maraviglia, Bruno
PY - 1994
Y1 - 1994
N2 - An extension of the Cartesian product operators formalism for scalar coupled I=1/2 and S=3 nuclear spins is proposed in order to predict the behavior of the function modulating the I spin echo amplitudes in spin-echo double resonance (SEDOR) experiments. With such an approach the coupling constant can be evaluated quite independently of the S=3 quadrupolar line broadening and magnetic field inhomogeneity. The method, which can be generalized to a wide class of molecules, is tested by the experimental behavior of the hydrogen SEDOR modulation by the 10B nuclei in Na210B 12H11SH.
AB - An extension of the Cartesian product operators formalism for scalar coupled I=1/2 and S=3 nuclear spins is proposed in order to predict the behavior of the function modulating the I spin echo amplitudes in spin-echo double resonance (SEDOR) experiments. With such an approach the coupling constant can be evaluated quite independently of the S=3 quadrupolar line broadening and magnetic field inhomogeneity. The method, which can be generalized to a wide class of molecules, is tested by the experimental behavior of the hydrogen SEDOR modulation by the 10B nuclei in Na210B 12H11SH.
UR - http://www.scopus.com/inward/record.url?scp=0004042109&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0004042109&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0004042109
VL - 101
SP - 4521
EP - 4525
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 6
ER -