Abstract
An extension of the Cartesian product operators formalism for scalar coupled I=1/2 and S=3 nuclear spins is proposed in order to predict the behavior of the function modulating the I spin echo amplitudes in spin-echo double resonance (SEDOR) experiments. With such an approach the coupling constant can be evaluated quite independently of the S=3 quadrupolar line broadening and magnetic field inhomogeneity. The method, which can be generalized to a wide class of molecules, is tested by the experimental behavior of the hydrogen SEDOR modulation by the 10B nuclei in Na210B 12H11SH.
Original language | English |
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Pages (from-to) | 4521-4525 |
Number of pages | 5 |
Journal | Journal of Chemical Physics |
Volume | 101 |
Issue number | 6 |
Publication status | Published - 1994 |
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics