Effect of peracetylation on the conformation of γ-cyclodextrin

Mino R. Caira; Giampiero Bettinetti; Milena Sorrenti; Laura Catenacci; Dyanne Cruickshank; Kate Davies

doi:10.1039/b616681d

Effect of peracetylation on the conformation of γ-cyclodextrin

Mino R. Caira, Giampiero Bettinetti, Milena Sorrenti, Laura Catenacci, Dyanne Cruickshank, Kate Davies

IRCCS Fondazione Policlinico San Matteo

Research output: Contribution to journal › Article

Abstract

The well-known, fourfold symmetry of the γ-CD molecule in its solid inclusion complexes is lost on peracetylation, which yields a highly distorted host molecule in which self-inclusion of acetyl residues divides the macrocyclic cavity into two distinct sub-cavities that accommodate solvent molecules.

Original language	English
Pages (from-to)	1221-1223
Number of pages	3
Journal	Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/b616681d
Publication status	Published - 2007

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ASJC Scopus subject areas

Chemistry(all)

Cite this

Caira, M. R., Bettinetti, G., Sorrenti, M., Catenacci, L., Cruickshank, D., & Davies, K. (2007). Effect of peracetylation on the conformation of γ-cyclodextrin. Chemical Communications, (12), 1221-1223. https://doi.org/10.1039/b616681d

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Access to Document

10.1039/b616681d