Entropy-mediated patterning of surfactant-coated nanoparticles and surfaces

Chetana Singh, Pradip K. Ghorai, Mark A. Horsch, Alicia M. Jackson, Ronald G. Larson, Francesco Stellacci, Sharon C. Glotzer

Research output: Contribution to journalArticlepeer-review

Abstract

We perform atomistic and mesoscale simulations to explain the origin of experimentally observed stripelike patterns formed by immiscible ligands coadsorbed on the surfaces of gold and silver nanoparticles. We show that when the conformational entropy gained via this morphology is sufficient, microphase-separated stripelike patterns form. When the entropic gain is not sufficient, we instead predict bulk phase-separated Janus particles. We also show corroborating experimental results that confirm our simulational predictions that stripes form on flat surfaces as well as on curved nanoparticle surfaces.

Original languageEnglish
Article number226106
JournalPhysical Review Letters
Volume99
Issue number22
DOIs
Publication statusPublished - Nov 30 2007

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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