High-performance liquid displacement chromatography of enantiomers on a chiral poly-l-valyl-based stationary phase

M. Slnibaldi, L. Castellani, F. Federici, A. Messina

Research output: Contribution to journalArticle

Abstract

A direct enantiomer separation according to the displacement mode of liquid chromatography has been developed on a silica-based stationary phase bearing as chiral selectors poly-L-valyl groups. Milligram amount resolution of DL-methionine β naphthylamide was accomplished on two analytical size columns using methanol containing acetate buffer as the carrier and DL mandelic acid dissolved in the carrier as the displacer.

Original languageEnglish
Pages (from-to)2977-2992
Number of pages16
JournalJournal of Liquid Chromatography
Volume16
Issue number14
DOIs
Publication statusPublished - Sep 1 1993

ASJC Scopus subject areas

  • Molecular Medicine

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