Abstract
The azobenzene unit used as a photochemically and thermally switchable linker in the assembly of a bis-calix[4]pyrrole receptor provides a means to modulate the binding of bis-carboxylates of significant biological importance in cancer research. Conversely, the complexation of different bis-anionic guests has significant kinetic effects on both the photochemical and thermal trans/cis isomerization of the azobenzene unit.
| Original language | English |
|---|---|
| Pages (from-to) | 5323-5327 |
| Number of pages | 5 |
| Journal | Chemistry - A European Journal |
| Volume | 21 |
| Issue number | 14 |
| DOIs | |
| Publication status | Published - Mar 27 2015 |
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Keywords
- anion binding
- azocompounds
- calixpyrroles
- carboxylates
- host-guest systems
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Host-guest chemistry of a bis-calix[4]pyrrole derivative containing a trans/cis-switchable azobenzene unit with several aliphatic bis-carboxylates. / Cafeo, Grazia; Kohnke, Franz H.; Mezzatesta, Giovanni; Profumo, Aldo; Rosano, Camillo; Villari, Antonino; White, Andrew J P.
In: Chemistry - A European Journal, Vol. 21, No. 14, 27.03.2015, p. 5323-5327.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Host-guest chemistry of a bis-calix[4]pyrrole derivative containing a trans/cis-switchable azobenzene unit with several aliphatic bis-carboxylates
AU - Cafeo, Grazia
AU - Kohnke, Franz H.
AU - Mezzatesta, Giovanni
AU - Profumo, Aldo
AU - Rosano, Camillo
AU - Villari, Antonino
AU - White, Andrew J P
PY - 2015/3/27
Y1 - 2015/3/27
N2 - The azobenzene unit used as a photochemically and thermally switchable linker in the assembly of a bis-calix[4]pyrrole receptor provides a means to modulate the binding of bis-carboxylates of significant biological importance in cancer research. Conversely, the complexation of different bis-anionic guests has significant kinetic effects on both the photochemical and thermal trans/cis isomerization of the azobenzene unit.
AB - The azobenzene unit used as a photochemically and thermally switchable linker in the assembly of a bis-calix[4]pyrrole receptor provides a means to modulate the binding of bis-carboxylates of significant biological importance in cancer research. Conversely, the complexation of different bis-anionic guests has significant kinetic effects on both the photochemical and thermal trans/cis isomerization of the azobenzene unit.
KW - anion binding
KW - azocompounds
KW - calixpyrroles
KW - carboxylates
KW - host-guest systems
UR - http://www.scopus.com/inward/record.url?scp=84925114731&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84925114731&partnerID=8YFLogxK
U2 - 10.1002/chem.201406183
DO - 10.1002/chem.201406183
M3 - Article
AN - SCOPUS:84925114731
VL - 21
SP - 5323
EP - 5327
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
SN - 0947-6539
IS - 14
ER -