Multifunctional bionanocomposite films of poly(lactic acid), cellulose nanocrystals and silver nanoparticles

E. Fortunati, I. Armentano, Q. Zhou, A. Iannoni, E. Saino, L. Visai, L. A. Berglund, J. M. Kenny

Research output: Contribution to journalArticle

Abstract

Nanocomposite films were prepared by the addition of cellulose nanocrystals (CNCs) eventually surfactant modified (s-CNC) and silver (Ag) nanoparticles in the polylactic acid (PLA) matrix using melt extrusion followed by a film formation process. Multifunctional composite materials were investigated in terms of morphological, mechanical, thermal and antibacterial response. The nanocomposite films maintained the transparency properties of the PLA matrix. Thermal analysis showed increased values of crystallinity in the nanocomposites, more evident in the s-CNC based formulations that had the highest tensile Young modulus. The presence of surfactant favoured the dispersion of cellulose nanocrystals in the polymer matrix and the nucleation effect was remarkably enhanced. Moreover, an antibacterial activity against Staphylococcus aureus and Escherichia coli cells was detected for ternary systems, suggesting that these novel nanocomposites may offer good perspectives for food packaging applications which require an antibacterial effect constant over time.

Original languageEnglish
Pages (from-to)1596-1605
Number of pages10
JournalCarbohydrate Polymers
Volume87
Issue number2
DOIs
Publication statusPublished - Jan 15 2012

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Keywords

  • Antibacterial response
  • Nanocomposite
  • Nanocrystalline cellulose
  • Polylactic acid

ASJC Scopus subject areas

  • Organic Chemistry
  • Materials Chemistry
  • Polymers and Plastics

Cite this

Fortunati, E., Armentano, I., Zhou, Q., Iannoni, A., Saino, E., Visai, L., Berglund, L. A., & Kenny, J. M. (2012). Multifunctional bionanocomposite films of poly(lactic acid), cellulose nanocrystals and silver nanoparticles. Carbohydrate Polymers, 87(2), 1596-1605. https://doi.org/10.1016/j.carbpol.2011.09.066