Palladium-catalyzed alkynylation

Ei Ichi Negishi, Luigi Anastasia

Research output: Contribution to journalArticlepeer-review


A brief overview of the scope of the four major protocols with respect to the electrophilic cross-coupling partners is presented in somewhat irrespective of relative merit and demerits among these protocols. Thus, some noteworthy recent advances in which more critical comparisons among the four protocols mentioned will made are discussed. In addition, some recent methodological developments with emphasis on searches for superior phosphine and other ligands as well as one mechanistic aspects of the Pd-catalyzed alkynylation are discussed as well.

Original languageEnglish
Pages (from-to)1979-2017
Number of pages39
JournalChemical Reviews
Issue number5
Publication statusPublished - May 2003

ASJC Scopus subject areas

  • Chemistry(all)


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