Quantitative analysis of scanning tunneling microscopy images of mixed-ligand-functionalized nanoparticles

Fabio Biscarini, Quy Khac Ong, Cristiano Albonetti, Fabiola Liscio, Maria Longobardi, Kunal S. Mali, Artur Ciesielski, Javier Reguera, Christoph Renner, Steven De Feyter, Paolo Samorì, Francesco Stellacci

Research output: Contribution to journalArticle

Abstract

Ligand-protected gold nanoparticles exhibit large local curvatures, features rapidly varying over small scales, and chemical heterogeneity. Their imaging by scanning tunneling microscopy (STM) can, in principle, provide direct information on the architecture of their ligand shell, yet STM images require laborious analysis and are challenging to interpret. Here, we report a straightforward, robust, and rigorous method for the quantitative analysis of the multiscale features contained in STM images of samples consisting of functionalized Au nanoparticles deposited onto Au/mica. The method relies on the analysis of the topographical power spectral density (PSD) and allows us to extract the characteristic length scales of the features exhibited by nanoparticles in STM images. For the mixed-ligand-protected Au nanoparticles analyzed here, the characteristic length scale is 1.2 ± 0.1 nm, whereas for the homoligand Au NPs this scale is 0.75 ± 0.05 nm. These length scales represent spatial correlations independent of scanning parameters, and hence the features in the PSD can be ascribed to a fingerprint of the STM contrast of ligand-protected nanoparticles. PSD spectra from images recorded at different laboratories using different microscopes and operators can be overlapped across most of the frequency range, proving that the features in the STM images of nanoparticles can be compared and reproduced.

Original languageEnglish
Pages (from-to)13723-13734
Number of pages12
JournalLangmuir
Volume29
Issue number45
DOIs
Publication statusPublished - Nov 12 2013

ASJC Scopus subject areas

  • Electrochemistry
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Materials Science(all)
  • Spectroscopy

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    Biscarini, F., Ong, Q. K., Albonetti, C., Liscio, F., Longobardi, M., Mali, K. S., Ciesielski, A., Reguera, J., Renner, C., De Feyter, S., Samorì, P., & Stellacci, F. (2013). Quantitative analysis of scanning tunneling microscopy images of mixed-ligand-functionalized nanoparticles. Langmuir, 29(45), 13723-13734. https://doi.org/10.1021/la403546c