Self-assembled monolayer of short carboxyl-terminated molecules investigated with ex situ scanning tunneling microscopy

Cedric Dubois, Francesco Stellacci

Research output: Contribution to journalArticle

Abstract

Self-assembled monolayers (SAMs) of thiolated molecules have numerous potential applications and are ideal models for complex supramolecular systems. The structure of these two-dimensional crystals is not understood fully yet and deserves in-depth investigations. Here we show that a short carboxylic acid ω-terminated molecule (3-mercaptopropionic acid, MPA) forms highly ordered SAMs on Au(111) surfaces. Molecular resolution scanning tunneling microscopy (STM) images were taken at room temperature in air (ex situ). They showed a √3 × √3 unit cell that, when imaged at high set current, appears reconstructed as a c(4 × 2) superlattice. This structure is quantitatively the same as that of intermediate-length alkane thiols, but is different from the structure found previously for SAMs of the same molecule investigated with liquid-STM during the formation of the monolayer (in situ). This work highlights the possibility for a short ω-terminated molecule to form ordered monolayers over large areas with few defects.

Original languageEnglish
Pages (from-to)7431-7435
Number of pages5
JournalJournal of Physical Chemistry C
Volume112
Issue number19
DOIs
Publication statusPublished - May 15 2008

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Scanning tunneling microscopy
Self assembled monolayers
scanning tunneling microscopy
Molecules
molecules
Monolayers
3-Mercaptopropionic Acid
Alkanes
Carboxylic Acids
complex systems
Carboxylic acids
Sulfhydryl Compounds
thiols
carboxylic acids
Paraffins
alkanes
Defects
Crystals
acids
Acids

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Energy(all)

Cite this

Self-assembled monolayer of short carboxyl-terminated molecules investigated with ex situ scanning tunneling microscopy. / Dubois, Cedric; Stellacci, Francesco.

In: Journal of Physical Chemistry C, Vol. 112, No. 19, 15.05.2008, p. 7431-7435.

Research output: Contribution to journalArticle

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