Solvent effects on the formation equilibria of cobalt(II)-chloride system in acetone-water mixture

V. Carunchio, U. Biader Ceipidor, A. Messina

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The data about cobalt(II) - chloride complexes in acetone solution have been completed by recent spectrophotometric methods (K3=4.5 107; K4=6.1 102). Furthermore, the influence of water addition on the system has been pointed out by considering the dielectric and donor properties of the solvent mixture. The results show a linear correlation of the complex species distribution with the reciprocal dielectric constant of the simple binary system, so that a possible explanation of the present data and of those of some oher authors has been discussed in terms of DEC influence on dissociation reactions. Donor number equality for water and acetone has made it possible to minimize the solvent influence on the ionization processes when varying water-acetone ratio.

Original languageEnglish
Pages (from-to)613-618
Number of pages6
JournalInorganica Chimica Acta
Volume6
Issue numberC
DOIs
Publication statusPublished - 1972

Fingerprint

Acetone
acetone
Cobalt
cobalt
chlorides
Water
water
Ionization
dielectric properties
Permittivity
dissociation
permittivity
ionization
cobaltous chloride

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Solvent effects on the formation equilibria of cobalt(II)-chloride system in acetone-water mixture. / Carunchio, V.; Ceipidor, U. Biader; Messina, A.

In: Inorganica Chimica Acta, Vol. 6, No. C, 1972, p. 613-618.

Research output: Contribution to journalArticle

@article{3f43c8eb0767489084c58b80ac428bb6,
title = "Solvent effects on the formation equilibria of cobalt(II)-chloride system in acetone-water mixture",
abstract = "The data about cobalt(II) - chloride complexes in acetone solution have been completed by recent spectrophotometric methods (K3=4.5 107; K4=6.1 102). Furthermore, the influence of water addition on the system has been pointed out by considering the dielectric and donor properties of the solvent mixture. The results show a linear correlation of the complex species distribution with the reciprocal dielectric constant of the simple binary system, so that a possible explanation of the present data and of those of some oher authors has been discussed in terms of DEC influence on dissociation reactions. Donor number equality for water and acetone has made it possible to minimize the solvent influence on the ionization processes when varying water-acetone ratio.",
author = "V. Carunchio and Ceipidor, {U. Biader} and A. Messina",
year = "1972",
doi = "10.1016/S0020-1693(00)91867-X",
language = "English",
volume = "6",
pages = "613--618",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier BV",
number = "C",

}

TY - JOUR

T1 - Solvent effects on the formation equilibria of cobalt(II)-chloride system in acetone-water mixture

AU - Carunchio, V.

AU - Ceipidor, U. Biader

AU - Messina, A.

PY - 1972

Y1 - 1972

N2 - The data about cobalt(II) - chloride complexes in acetone solution have been completed by recent spectrophotometric methods (K3=4.5 107; K4=6.1 102). Furthermore, the influence of water addition on the system has been pointed out by considering the dielectric and donor properties of the solvent mixture. The results show a linear correlation of the complex species distribution with the reciprocal dielectric constant of the simple binary system, so that a possible explanation of the present data and of those of some oher authors has been discussed in terms of DEC influence on dissociation reactions. Donor number equality for water and acetone has made it possible to minimize the solvent influence on the ionization processes when varying water-acetone ratio.

AB - The data about cobalt(II) - chloride complexes in acetone solution have been completed by recent spectrophotometric methods (K3=4.5 107; K4=6.1 102). Furthermore, the influence of water addition on the system has been pointed out by considering the dielectric and donor properties of the solvent mixture. The results show a linear correlation of the complex species distribution with the reciprocal dielectric constant of the simple binary system, so that a possible explanation of the present data and of those of some oher authors has been discussed in terms of DEC influence on dissociation reactions. Donor number equality for water and acetone has made it possible to minimize the solvent influence on the ionization processes when varying water-acetone ratio.

UR - http://www.scopus.com/inward/record.url?scp=49649140853&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=49649140853&partnerID=8YFLogxK

U2 - 10.1016/S0020-1693(00)91867-X

DO - 10.1016/S0020-1693(00)91867-X

M3 - Article

VL - 6

SP - 613

EP - 618

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

IS - C

ER -