Synthesis of 5(10→9)abeo-ergolines

Sergio Mantegani, Emanuele Arlandini, Daniela Borghi, Enzo Brambilla, Mario Varasi

Research output: Contribution to journalArticlepeer-review

Abstract

Reaction of the (5 R, 8 R)-ergoline derivative (6) with the couple CCl4/(Ph)3P unexpectedly resulted in the formation of the novel (5 S, 8 R)-5 (10→9)abeo-ergoline derivative. A mechanism of this transposition process is proposed.

Original languageEnglish
Pages (from-to)1493-1506
Number of pages14
JournalHeterocycles
Volume45
Issue number8
Publication statusPublished - 1997

ASJC Scopus subject areas

  • Organic Chemistry

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