Synthesis of 5(10→9)abeo-ergolines

Sergio Mantegani; Emanuele Arlandini; Daniela Borghi; Enzo Brambilla; Mario Varasi

Synthesis of 5(10→9)abeo-ergolines

Sergio Mantegani, Emanuele Arlandini, Daniela Borghi, Enzo Brambilla, Mario Varasi

Istituto Europeo di Oncologia

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of the (5 R, 8 R)-ergoline derivative (6) with the couple CCl₄/(Ph)₃P unexpectedly resulted in the formation of the novel (5 S, 8 R)-5 (10→9)abeo-ergoline derivative. A mechanism of this transposition process is proposed.

Original language	English
Pages (from-to)	1493-1506
Number of pages	14
Journal	Heterocycles
Volume	45
Issue number	8
Publication status	Published - 1997

ASJC Scopus subject areas

Organic Chemistry

Cite this

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title = "Synthesis of 5(10→9)abeo-ergolines",

abstract = "Reaction of the (5 R, 8 R)-ergoline derivative (6) with the couple CCl4/(Ph)3P unexpectedly resulted in the formation of the novel (5 S, 8 R)-5 (10→9)abeo-ergoline derivative. A mechanism of this transposition process is proposed.",

author = "Sergio Mantegani and Emanuele Arlandini and Daniela Borghi and Enzo Brambilla and Mario Varasi",

year = "1997",

language = "English",

volume = "45",

pages = "1493--1506",

journal = "Heterocycles",

issn = "0385-5414",

publisher = "Japan Institute of Heterocyclic Chemistry",

number = "8",

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TY - JOUR

T1 - Synthesis of 5(10→9)abeo-ergolines

AU - Mantegani, Sergio

AU - Arlandini, Emanuele

AU - Borghi, Daniela

AU - Brambilla, Enzo

AU - Varasi, Mario

PY - 1997

Y1 - 1997

N2 - Reaction of the (5 R, 8 R)-ergoline derivative (6) with the couple CCl4/(Ph)3P unexpectedly resulted in the formation of the novel (5 S, 8 R)-5 (10→9)abeo-ergoline derivative. A mechanism of this transposition process is proposed.

AB - Reaction of the (5 R, 8 R)-ergoline derivative (6) with the couple CCl4/(Ph)3P unexpectedly resulted in the formation of the novel (5 S, 8 R)-5 (10→9)abeo-ergoline derivative. A mechanism of this transposition process is proposed.

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M3 - Article

AN - SCOPUS:0001509729

VL - 45

SP - 1493

EP - 1506

JO - Heterocycles

JF - Heterocycles

SN - 0385-5414

IS - 8

ER -

Synthesis of 5(10→9)abeo-ergolines

Abstract

ASJC Scopus subject areas

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